Transition Metal Hydrides
1st Edition
Published on 6. December 1991
Book
Hardback
416 pages
978-0-471-18768-4 (ISBN)
Description
Internationally renowned authors review recent advances in the understanding of the structure and reactivity of transition metal hydrides. This up-to-date analysis of transition metal hydrides examines the recent upsurge of experimental studies devoted to transition metal hydrides in both gas phase and solution. It also explores the recent emergence of new refinements in the methodologies and techniques used to delineate reaction mechanisms in solution.
More details
Product info
GB
Edition
1., Auflage
Language
English
Place of publication
United States
Publishing group
John Wiley & Sons Inc
Target group
College/higher education
Professional and scholarly
Metallorganiker, Komplexchemiker, Theoretische Chemiker, Chemische Institute, Institutsbibliotheken
Product notice
sewn/stitched
Cloth over boards
Illustrations
93
52 s/w Abbildungen, 41 s/w Tabellen
Dimensions
Height: 240 mm
Width: 161 mm
Thickness: 27 mm
Weight
783 gr
ISBN-13
978-0-471-18768-4 (9780471187684)
Schweitzer Classification
Person
A. Dedieu is the author of Transition Metal Hydrides, published by Wiley.
Content
1. Introduction to Transition Metal Hydrides What is a Transition Metal Hydride?
Importance of Transition Metal Hydrides in Catalysis
Theoretical Approaches to Studying Metal Hydrides (DFT, MO Theory)
2. Electronic Structure and Bonding
Metal-Hydrogen Bond Character
Back-Donation and its Influence on Stability
Factors Affecting Hydride Stability (Metal Oxidation State, Ligand Effects)
3. Structural Features of Transition Metal Hydrides
Coordination Geometry and Hydride Position
X-ray Crystallography and Neutron Diffraction Studies
Spectroscopic Characterization (NMR, IR)
4. Formation of Transition Metal Hydrides Oxidative Addition of H2, Heterolytic Cleavage of H2, and Protonation of a Metal Complex.
5. Reactivity of Transition Metal Hydrides
Insertion Reactions (CO, Olefins)
Reductive Elimination
Hydrogen Transfer Reactions
Beta-Hydride Elimination
6. Catalytic Applications of Transition Metal Hydrides
Hydrogenation Reactions (Alkenes, Alkynes, Carbonyl Compounds)
Hydrosilylation
Hydroboration
Asymmetric Catalysis
7. Selected Case Studies The Wilkins on Catalyst (Rh-based), The Crabtree Catalyst (Ir-based), and Metal Hydrides in Polymerization Reactions.
8. Recent Advances and Future Directions Computational Modeling of Hydride Reactivity, Development of New Catalysts for Hydrogen Storage, and Biomimetic Hydride Transfer Systems.
Importance of Transition Metal Hydrides in Catalysis
Theoretical Approaches to Studying Metal Hydrides (DFT, MO Theory)
2. Electronic Structure and Bonding
Metal-Hydrogen Bond Character
Back-Donation and its Influence on Stability
Factors Affecting Hydride Stability (Metal Oxidation State, Ligand Effects)
3. Structural Features of Transition Metal Hydrides
Coordination Geometry and Hydride Position
X-ray Crystallography and Neutron Diffraction Studies
Spectroscopic Characterization (NMR, IR)
4. Formation of Transition Metal Hydrides Oxidative Addition of H2, Heterolytic Cleavage of H2, and Protonation of a Metal Complex.
5. Reactivity of Transition Metal Hydrides
Insertion Reactions (CO, Olefins)
Reductive Elimination
Hydrogen Transfer Reactions
Beta-Hydride Elimination
6. Catalytic Applications of Transition Metal Hydrides
Hydrogenation Reactions (Alkenes, Alkynes, Carbonyl Compounds)
Hydrosilylation
Hydroboration
Asymmetric Catalysis
7. Selected Case Studies The Wilkins on Catalyst (Rh-based), The Crabtree Catalyst (Ir-based), and Metal Hydrides in Polymerization Reactions.
8. Recent Advances and Future Directions Computational Modeling of Hydride Reactivity, Development of New Catalysts for Hydrogen Storage, and Biomimetic Hydride Transfer Systems.