Spectroscopic Properties of Inorganic and Organometallic Compounds

Chapter 1: NMR Spectroscopy in the Liquid and Gas Phases;

1: Introduction;

2: Stereochemistry;

2.1: Compounds of Group 1;

2.2: Compounds of Group 2;

2.3: Compounds of Group 3 (Yttrium, Lanthanides, Actinides);

2.4: Compounds of Group 4;

2.5: Compounds of Group 5;

2.6: Compounds of Group 6;

2.7: Compounds of Group 7;

2.8: Compounds of Group 8;

2.9: Compounds of Group 9;

2.10: Compounds of Group 10;

2.11: Compounds of Group 11;

2.12: Compounds of Group 12;

2.13: Compounds of Group 13;

2.14: Compounds of Group 14;

2.15: Compounds of Group 15;

2.16: Compounds of Group 16;

2.17: Compounds of Group 17;

2.18: Compounds of Group 18;

3: Dynamic Systems;

3.1: Fluxional Molecules;

3.2: Equilibrium Processes;

3.3: Course of Reactions;

4: Paramagnetic Complexes;

4.1: The Transition Metals;

4.2: Lanthanides and Actinides;

References;

Chapter 2: Solid State NMR Spectroscopy;

1: Structure of Solids;

1.1: Group 1;

1.2: Group 2;

1.3: Group 3;

1.4: Group 4;

1.5: Group 5;

1.6: Group 6;

1.7: Group 7;

1.8: Group 8;

1.9: Group 9;

1.10: Group 10;

1.11: Group 11;

1.12: Group 12;

1.13: Group 13;

1.14: Group 14;

1.15: Group 15;

1.16: Group 16;

1.17: Group 18;

2: Motions in Solids;

3: Atoms and Molecules Sorbed onto Solids;

3.1: Water Sorbed onto Solids;

3.2: Other Sorbed Atoms and Molecules;

References;

Chapter 3: Nuclear Quadrupole Resonance Spectroscopy;

1: Introduction;

2: Main Group Elements;

2.1: Group 1 (Lithium-8);

2.2: Group 13 (Boron-11 and -12, Gallium-69 and -71, and Indium-115);

2.3: Group 14 (Germanium-73);

2.4: Group 15 (Nitrogen-14, Arsenic-75, Antimony-121 and -123, and Bismuth-209);

2.5: Group 17 (Chlorine-35 and -37, Bromine 79 and 81, and Iodine-127);

3: Transition Metals and Lanthanides;

3.1: Manganese-55;

3.2: Cobalt-59;

3.3: Copper-63 and -65;

3.4: Lanthanum-139;

3.5: Rhenium-187;

References;

Chapter 4: Characteristic Vibrations of Compounds of Main Group Elements;

1: Group 1;

2: Group 2;

3: Group 13;

3.1: Boron;

3.2: Aluminium;

3.3: Gallium;

3.4: Indium;

3.5: Thallium;

4: Group 14;

4.1: Carbon;

4.2: Silicon;

4.3: Germanium;

4.4: Tin;

4.5: Lead;

5: Group 15;

5.1: Nitrogen;

5.2: Phosphorus;

5.3: Arsenic;

5.4: Antimony;

5.5: Bismuth;

6: Group 16;

6.1: Oxygen;

6.2: Sulfur;

6.3: Selenium;

6.4: Tellurium;

7: Group 17;

8: Group 18;

References;

Chapter 5: Vibrational Spectra of Transition Element Compounds;

1: Scandium, Yttrium and the Lanthanides;

2: Titanium, Zirconium and Hafnium;

3: Vanadium, Niobium and Tantalum;

4: Chromium, Molybdenum and Tungsten;

5: Manganese, Technetium and Rhenium;

6: Iron, Ruthenium and Osmium;

7: Cobalt, Rhodium and Iridium;

8: Nickel, Palladium and Platinum;

9: Copper, Silver and Gold;

10: Zinc, Cadmium and Mercury;

11: Actinides;

References;

Chapter 6: Vibrational Spectra of Some Co-ordinated Ligands;

1: Carbon, Silicon, Germanium and Tin Donors;

2: Dihydrogen Complexes;

3: Boron Donors ;

4: Carbonyl and Thiocarbonyl Complexes;

5: Nitrogen Donors ;

5.1: Molecular Nitrogen, Azido- and Related Groups;

5.2: Amines and Related Ligands;

5.3: Ligands Containing >C=N- Groups;

5.4: Cyanides, Isocyanides and Related Complexes;

5.5 : Nitrosyl Complexes ;

6 : Phosphorus and Arsenic Donors;

7 : Oxygen Donors ;

7.1: Molecular Oxygen, Peroxo, Aquo and Related Complexes;

7.2: Carboxylate and Related Complexes;

7.3: Keto-, Alkoxy-, Ether and Related Complexes;

7.4: Ligands Containing O-N, O-P or O-As Bonds;

7.5: Ligands Containing O-S or O-Te Bonds;

7.6: Ligands Containing O-Cl or O-I Bonds;

8: Sulfur and Selenium Donors;

9: Potentially Ambident Ligands;

9.1: Cyanates, Thio- and Selenocyanates and Their Iso-analogues;

9.2: Ligands Containing N and O, N and P or P and O Donor Atoms;

9.3: Ligands Containing N and S, N and Se or P and S Donor Atoms;

9.4: Ligands Containing S and O Donor Atoms;

References;

Chapter 7: Gas-phase Molecular Structures Determined by Electron Diffraction;

1: Introduction;

2: Compounds of Elements in Group 2 and 13;

3: Compounds of Elements in Group 14;

4: Compounds of Elements in Group 15;

5: Compounds of Elements in Group 16;

6: Compounds of Transition Elements, Lanthanides and Actinides;

References