Introduction to Critical Phenomena in Fluids

1: Fundamentals of Thermodynamic Stability
1.1: Mathematical and Thermodynamic Preliminaries
1.2: Thermodynamic Stability Theory
1.3: Thermodynamic Conditions at the Limit of Stability
1.4: Equivalence of Stability Criteria between Different Thermodynamic Potentials
1.5: Further Use of Combined Theorems
1.6: Chapter Review
1.7: Additional Exercises
2: The Critical Point in Pure Fluids and Mixtures
2.1: The Critical Point: Pure Fluids
2.2: Generalization of the Results to Multicomponent Mixtures
2.3: Beyond the Limit of Stability
2.4: Chapter Review
3: Thermodynamic Scaling Near the Critical Point
3.1: The Classical Equation of State, Path Dependence, and Scaling at the Critical Point
3.2: The Various Critical Exponents and their Scaling Paths
3.3: Scaling in Terms of Kt, Cp, and ~p
3.4: The Griffiths-Wheeler Classification
3.5: The Direction of Approach to the Critical Point
3.6: Scaling Results from the Stable Limit of Stability Conditions
3.7: Chapter Review
3.8: Additional Exercises
4: Scaling Near the Critical Point Mixtures
4.1: The Critical-Line Topography in Binary Supercritical Mixtures