Application of Polarization Modulation Infrared Reflection Absorption Spectroscopy in Electrochemistry
Published on 12. June 2020
Book
Hardback
XII, 122 pages
978-3-030-42163-2 (ISBN)
Description
This book describes the physical basis of polarization modulation infrared reflection-absorption spectroscopy and its application in electrochemical studies. It provides a concise yet comprehensive review of the research done in this field in the last 20 years. Electrochemical methods are used to determine the rate and mechanism of charge transfer reactions between an electrode and species adsorbed or diffusing to its surface. In the past two decades PM-IRRAS has grown to be one of the most important vibrational spectroscopy techniques applied to investigate structural changes taking place at the electrochemical interface. The monograph presents foundations of this technique and reviews in situ studies of redox-inactive and redox-active films adsorbed on electrode surfaces. It also discusses experimental conditions required in electrochemical and spectroscopic studies and presents practical solutions to perform efficient experiments. As such, it offers an invaluable resource for graduate and postgraduate students, as well as for all researchers in academic and industrial laboratories.
More details
Product info
Book
Series
Edition
1st ed. 2020
Language
English
Place of publication
Cham
Switzerland
Publishing group
Springer International Publishing
Target group
Professional and scholarly
Illustrations
12 farbige Abbildungen, 18 farbige Tabellen, 52 s/w Abbildungen
18 Tables, color; 12 Illustrations, color; 52 Illustrations, black and white; XII, 122 p. 64 illus., 12 illus. in color.
Dimensions
Height: 241 mm
Width: 160 mm
Thickness: 14 mm
Weight
377 gr
ISBN-13
978-3-030-42163-2 (9783030421632)
DOI
10.1007/978-3-030-42164-9
Schweitzer Classification
Other editions
Additional editions
Izabella Brand
Application of Polarization Modulation Infrared Reflection Absorption Spectroscopy in Electrochemistry
Book
06/2021
Springer
€106.99
Shipment within 7-9 days
Izabella Brand
Application of Polarization Modulation Infrared Reflection Absorption Spectroscopy in Electrochemistry
E-Book
06/2020
1st Edition
Springer
€96.29
Available for download
Person
Izabella Brand is a Privatdozentin at the Carl von Ossietzky University of Oldenburg, Germany. She graduated in 1997 and obtained her PhD degree in chemistry in 2001 at the University of Warsaw, Poland. After graduation, she spent two years as a postdoctoral researcher at the University of Guelph, Canada. She then worked as research assistant at the Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland (2004-2005) and at the Carl von Ossietzky University of Oldenburg, Germany (2005-2014), where she habilitated in 2014. Dr. Brand is author and coauthor of almost 50 research papers, 2 book chapters and 1 book.
Content
Introduction
1. In situ infrared reflection-absorption spectroscopy at the electrode|electrolyte interface 1.1. Introduction to IRRAS 1.2. Reflection of the IR light from mirror surfaces 1.3. Introduction to the stratified systems 1.4. PM IRRAS: background of the technique, measured spectrum, deconvolution, background subtraction 1.5. Qualitative and quantitative analysis 1.6. Requirements of in situ experiments: Experimental conditions which have to be taken into consideration
2. PM IRRAS for studies of redox-inactive molecular films adsorbed on electrode surfaces 2.1. Redox-inactive films on electrodes: importance of these studies: biomimetic applications (predominantly) 2.2. In situ PM IRRAS of models of cell membranes 2.3. Cell membranes: supported lipid bilayers (LB-LS, vesicles), tethered lipid bilayers, floating lipid bilayers, role of composition, lateral and transverse symmetry 2.4. Interaction of cell membranes with proteins: channel forming proteins, anchor protein, interacting with a polar head group protein 2.5. In situ PM IRRAS of protein films2.6. In situ PM IRRAS of DNA-films 2.7. Other redox-inactive films: n-octadecanol, pyridine
3. PM IRRAS for studies of redox-active molecular films adsorbed on electrode surfaces 3.1. Redox-active films on electrodes: applications (catalysis, redox-active thin organized films, redox-active thick films) 3.2. Use of in situ PM IRRAS for studies of electrocatalytic processes 3.3. In situ PM IRRAS studies of thin organized films of redox-active molecules: metalloorganic compounds3.4. In situ PM IRRAS studies of thick, redox-active molecular films: polymer films 3.5. Redox-active films on electrodes: applications (catalysis, redox-active thin organized films, redox-active thick films) 3.6. Use of in situ PM IRRAS for studies of electrocatalytic processes3.7. In situ PM IRRAS studies of thin organized films of redox-active molecules: metalloorganic compounds3.8. In situ PM IRRAS studies of thick, redox-active molecular films: polymer films
1. In situ infrared reflection-absorption spectroscopy at the electrode|electrolyte interface 1.1. Introduction to IRRAS 1.2. Reflection of the IR light from mirror surfaces 1.3. Introduction to the stratified systems 1.4. PM IRRAS: background of the technique, measured spectrum, deconvolution, background subtraction 1.5. Qualitative and quantitative analysis 1.6. Requirements of in situ experiments: Experimental conditions which have to be taken into consideration
2. PM IRRAS for studies of redox-inactive molecular films adsorbed on electrode surfaces 2.1. Redox-inactive films on electrodes: importance of these studies: biomimetic applications (predominantly) 2.2. In situ PM IRRAS of models of cell membranes 2.3. Cell membranes: supported lipid bilayers (LB-LS, vesicles), tethered lipid bilayers, floating lipid bilayers, role of composition, lateral and transverse symmetry 2.4. Interaction of cell membranes with proteins: channel forming proteins, anchor protein, interacting with a polar head group protein 2.5. In situ PM IRRAS of protein films2.6. In situ PM IRRAS of DNA-films 2.7. Other redox-inactive films: n-octadecanol, pyridine
3. PM IRRAS for studies of redox-active molecular films adsorbed on electrode surfaces 3.1. Redox-active films on electrodes: applications (catalysis, redox-active thin organized films, redox-active thick films) 3.2. Use of in situ PM IRRAS for studies of electrocatalytic processes 3.3. In situ PM IRRAS studies of thin organized films of redox-active molecules: metalloorganic compounds3.4. In situ PM IRRAS studies of thick, redox-active molecular films: polymer films 3.5. Redox-active films on electrodes: applications (catalysis, redox-active thin organized films, redox-active thick films) 3.6. Use of in situ PM IRRAS for studies of electrocatalytic processes3.7. In situ PM IRRAS studies of thin organized films of redox-active molecules: metalloorganic compounds3.8. In situ PM IRRAS studies of thick, redox-active molecular films: polymer films