
Electron Paramagnetic Resonance Spectroscopy
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"The book targets graduate students and researchers who are interested in acquiring the broad background knowledge needed to interpret the spectra and understand the applications of EPR technique. A set of problems, with hints to solutions, covers a wide range of difficulty." (Christian Brosseau, Optics & Photonics News, osa-opn.org, October 1, 2020)
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Content
Preface.- Fundamental constants - Units conversion.- The electron paramagnetic resonance phenomenon.- Hyperfine structure of the spectrum in the isotropic regime.- Introduction to the spin states space formalism.- Consequences of the anisotropy of G and A matrices on the shape of spectra given by radicals and transition ions complexes.- Intensity of the spectrum, saturation, spin-lattice relaxation.- Zero field splitting. EPR spectra given by paramagnetic centers with spin greater than ½.- Effect of dipolar and exchange interactions on the EPR spectrum - Biradicals and polynuclear complexes.- EPR spectra given by rare earth and actinide complexes.- Effect of instrumental parameters on the shape and intensity of the spectrum - Introduction to numerical simulation techniques.