Stereochemistry of Organometallic and Inorganic Compounds: Chains, Clusters, Inclusion Compounds, Paramagnetic Labels and Organic Rings v. 5
Published in January 1994
Book
Hardback
678 pages
978-0-444-81581-1 (ISBN)
Description
The role of stereochemistry to elucidate reaction patterns and physicochemical properties in topical subjects ranging from inorganic to organic chemistry is the focus of this volume, the last in the series. Detailed accounts are given to study: chaining in polyphosphates. electron-transfers in carbonyl clusters, inclusion of organometallic molecules in cyclodextrins, stereochehmistry of paramagnetic metal complexes by labeling with nitroxyl radicals, stereocontrol in organic syntheses assisted by inorganic complexes.
More details
Series
Language
English
Place of publication
Oxford
United Kingdom
Publishing group
Elsevier Science & Technology
Target group
College/higher education
Professional and scholarly
Illustrations
references, notes, index
Dimensions
Height: 230 mm
ISBN-13
978-0-444-81581-1 (9780444815811)
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Additional editions
E-Book
12/2012
Elsevier
€70.95
Available for download
Content
1. Crystal Chemistry of Cyclophosphates (M.T. Averbuch-Pouchot, A. Durif). Cyclotriphosphates. Cyclotetraphosphates. Cyclopentaphosphates. Cyclohexaphosphates. Cyclooctaphosphates. Cyclodecaphosphates. Cycloduodeca-phosphates. Ring anions in mixed anion phosphates. Thiocyclophosphates. The P04 tetrahedron in cyclophosphates. References. 2. Stereochemical Aspects of the Redox Propensity of Homometal Carbonyl Clusters (P. Zanello). Iron clusters. Ruthenium clusters. Osmium clusters. Cobalt clusters. Rhodium clusters. Iridium clusters. Nickel clusters. Platinum clusters. Rhenium clusters. 3. Preparation, Properties, and Stereochemical Aspects of Inclusion Compounds of Organometallic Complexes with Cyclodextrins (A. Harada). Cyclodextrins. Ferrocene and its derivatives. Cyclopentadienyl (arene) complexes. (n6-Arene)tricarbonylchromium. Olefin complexes. pie-Allylpalladium complexes. Carborane. Metal carbonyl complexes. Phosphine complexes. Optical resolution. Inclusion complexes in solutions. Inverse phase transfer catalysis. Conclusion. References. 4. Metal-Nitroxyl Interactions as Probes of Stereochemistry (S.S. Eaton, G.R. Eaton). Spin-spin interaction in rapidly tumbling systems. Interaction in a rigid lattice. Summary and prognosis. Acknowledgement. 5. Recent Developments on Stereocontrol Via (n6-Arene)Chromium Complexes (M. Uemura). Stereocontrol in cyclic arene chromium complexes. Diastereoselective synthesis of (ortho-substituted benzylalcohol)chromium complexes. Stereospecific carbon-carbon bond formation via Cr(CO)s-stabilized carbocations in acyclic series. Diastereoselective Cr(CO)3 complexation assisted by a remote hydroxyl group. Diastereoselective aldol reaction of (ortho-substituted acetophenone)chromium complexes. Diastereoselective 1,4-addition of or(yanocopper reagents to (ortho-substituted phenyl (E)-enone)chromium complexes. Remote stereocontrol via (arene)chromium complexes. Diastereoselective addition of crotyl metal to Cr(CO)3-complexed aromatic ketones. [2,3]-Wittig sigmatropic rearrangement of Cr(CO)3-complexed benzyl crotyl ethers. Total synthesis of (+ )-dihydroxyserrulatic acid via (arene)chromium complexes. Optically active (arene) chromium complexes and their utility in catalytic asymmetric synthesis. 6. The Stereochemistry of Palladium Catalyzed Cyclization Reactions (A. Heumann). Addition to carbon-carbon double bonds (7t-route).