Efficient Methods for Preparing Silicon Compounds

 
 
Academic Press
  • 1. Auflage
  • |
  • erschienen am 12. Mai 2016
  • |
  • 538 Seiten
 
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978-0-12-803568-9 (ISBN)
 

Efficient Methods for Preparing Silicon Compounds is a unique and valuable handbook for chemists and students involved in advanced studies of preparative chemistry in academia and industry. Organized by the various coordination numbers (from two to six) of the central silicon atom of the reported compounds, this book provides researchers with a handy and immediate reference for any compound or properties needed in the area.

Edited by a renowned expert in the field, each chapter explores a different type of compound, thoroughly illustrated with useful schemes and supplemented by additional references. Knowledgeable contributors report on a broad range of compounds on which they have published and which are already used on a broad scale or have the potential to be used in the very near future to develop a new field of research or application in silicon chemistry.


  • Includes contributions and edits from leading experts in the field
  • Includes detailed chemical schemes and useful references for each preparative method
  • Organized by the coordination numbers of the central silicon atom for each compound for easy navigation
  • Serves as a go-to primer for researchers in novel compositions of silicon matter


Herbert W. Roesky is an Emeritus Professor for Inorganic and Organometallic Chemistry with a broad experience in materials chemistry, homogeneous catalysis, fluorine, aluminum, and silicon chemistry as well as chemical education. In the tradition of great European chemical lecture demonstrations, he has given experimental lectures all over the world. His leadership in the above mentioned fluorine field is demonstrated with the international Henri Moissan Fluorine Award of France and the Fluorine Award of the American Chemical Society. For his scientific work of compounds with low valent aluminum, homogeneous catalysis, and new materials, he received from Germany the Alfred Stock Memorial Award and the Leibniz Award, from the Royal Society of Chemistry the Centenary Medal, from France the Grand Prix de la Fondation de la Maison de la Chimie and the Wittig-Grignard Lectureship, and from the American Chemical Society the Inorganic Award. The Indian Chemical Society of Research awarded him with the Rao Lectureship. These awards and recognitions in a number of countries demonstrate his independent scientific leadership of outstanding quality in research. After his retirement, he on started the chemistry of low valent silicon. The results have found international recognition due to their unique and unforeseen properties. The number of topics show his broad vision of modern and important developments especially in multidisciplinary research.
  • Englisch
  • Atlanta
  • |
  • USA
Elsevier Science
  • 20,47 MB
978-0-12-803568-9 (9780128035689)
0128035684 (0128035684)
weitere Ausgaben werden ermittelt
  • Front Cover
  • EFFICIENT METHODS FOR PREPARING SILICON COMPOUNDS
  • EFFICIENT METHODS FOR PREPARING SILICON COMPOUNDS
  • Copyright
  • Dedication
  • CONTENTS
  • LIST OF CONTRIBUTORS
  • PREFACE
  • 1 - ARYLSILANES AS PRECURSORS OF CYCLOHEXA-2,5-DIENYLSILANES
  • Preparation of cyclohexa-2,5-dienyldimethylsilanol
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Application
  • References
  • 2 - RHODIUM-CATALYZED VINYLDIAZOESTERS INSERTION INTO SIH BONDS. SYNTHESIS OF ALLYLSILANES
  • Preparation of methyl (Z)-2-(dimethylphenylsilyl)non-3-enoate
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Attention!
  • Application
  • References
  • 3 - LEWIS BASE-STABILIZED SILYLIUMS
  • Preparation of the binaphthylsilylium ion
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Attention!
  • Application
  • References
  • 4 - TETRA(SILYL)METHANE, (H3SI)4C, A VOLATILE CARBOSILANE FOR THE CHEMICAL VAPOR DEPOSITION OF AMORPHOUS SILICON CARBIDE TH ...
  • Synthesis protocols
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Applications
  • References
  • 5 - TRIMETHYLSILYL PERRHENATE-A NONIONIC REAGENT SOLUBLE IN ORGANIC SOLVENTS FOR THE PREPARATION OF PERRHENATES
  • Preparative routes
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Applications
  • References
  • 6 - RADICALS, ANIONS, AND CATIONS OF SILICON AND SILYLENES
  • 6.1 SILYL RADICALS
  • 6.1.1 Silylene Anion Radical: [Bis(1,4,7,10-tetraoxacyclododecane)lithium(1)]-1,1,3,3-tetra-tbutyl-1,3-dimethyltrisilane-2-yl-2-ylide
  • Synthesis of silylene anion radical: [bis(1,4,7,10-tetraoxacyclododecane)lithium(1)]-1,1,3,3-tetra-tbutyl-1,3-dimethyltrisi ...
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Attention!
  • Application
  • References
  • 6.1.2 Disilene Anion Radical: [Lithium(tetrahydrofuran)4]+ Tetrakis(di-tbutylmethylsilyl)disilene Anion Radical
  • Preparation of [lithium(tetrahydrofuran)4]+ tetrakis(di-tbutylmethylsilyl)disilene anion radical
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Attention!
  • Application
  • References
  • 6.1.3 Disilene Cation Radical: Tetrakis(di-tbutylmethylsilyl)disilene Cation Radical Tetrakis(pentafluorophenyl)borate
  • Preparation of disilene cation radical
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Application
  • References
  • 6.1.4 Silyl Radical: 1,1,3,3-tetra-tbutyl-1,3-dimethyl-2-[(1,4,7,10,13-pentaoxacyclopentadecane)sodium]trisilan-2-yl
  • Synthesis of silyl radical (tBu2MeSi)2SiNa
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Application
  • References
  • 6.2 SILYL ANIONS
  • 6.2.1 Two Disilenyllithium Compounds: 1,1-Bis(di-tbutylmethylsilyl)-2-lithio-2-di-tbutylmethylsilyldisilene and 1,1-Bis(di-tbutyl ...
  • Disilenyllithium 1: 1,1-bis(di-tbutylmethylsilyl)-2-lithio-2-di-tbutylmethylsilyldisilene
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Disilenyllithium 2: 1,1-bis(di-tbutyl methylsilyl)-2-lithio-2-mesityldisilene
  • Preparation of tetrasila-1,3-butadiene: (tBu2MeSi)2SiSi(Mes)(Mes)SiSi(SiMetBu2)2
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of disilenyllithium 2: 1,1-bis(di-tbutylmethylsilyl)-2-lithio-2-mesityldisilene
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Attention!
  • Application
  • Preparation of boryl-substituted disilene
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • References
  • 6.2.2 A (?3-Disilaallyl)lithium Derivative: [(tBu2MeSi)2SiSi(OSiMetBu2)C(CAr3)H]Li(THF)
  • Ar = 3,5-tBu-C6H3)
  • Preparation of the precursors
  • Preparation of tris(3,5-di-tbutylphenyl)acetic acid
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of 2,2,2-tris(3,5-(di-tbutylphenyl)-1-ethanol
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of tris(3,5-di-tbutylphenyl)acetaldehyde
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of (?3-disilaallyl)lithium derivative
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Attention!
  • Waste disposal
  • Attention!
  • Application
  • References
  • 6.3 SILYL CATIONS
  • 6.3.1 Cyclotetrasilenylium Ion: 1,3,4,4-Tetra-tbutyl-2-(di-tbutylmethylsilyl)Cyclotetrasilenylium
  • Preparation of 1,3,4,4-tetra-tbutyl-2-(di-tbutylmethylsilyl)cyclotetrasilenylium
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Application
  • References
  • 6.3.2 NHC-Stabilized Silyliumylidene [m-TerSi(Me4NHC)2]Cl and NHC-Stabilized Sila-Acylium Ion [m-TerSi(Me4NHC)2O]Cl
  • {m-Ter = 2,6 ...
  • Preparation of NHC-stabilized silyliumylidene ion: [m-TerSi(Me4NHC)2]Cl
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Attention!
  • Application
  • Preparation of NHC-stabilized sila-acylium ion: [m-TerSi(Me4NHC)2O]Cl
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • References
  • 6.3.3 Chlorosilyliumylidene [(bNHC)SiCl]+Cl-as a Precursor for Cyclic Silylone (Sila-Dicarbene) [(bNHC)Si]
  • (bNHC = 1,1´-Methylen ...
  • Synthesis of bNHC ligand
  • Synthesis of 1,1´-methylene-3,3´-di-2,6-diisopropylphenylimidazolium dibromide (ImBr2)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Synthesis of bNHC
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Synthesis of chlorosilyliumylidene
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Application
  • Synthesis of silylone
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Application
  • References
  • 6.4 SILYLENES
  • 6.4.1 Ylide-Stabilized Carbocyclic Silylene: a,a´-Bis(tri-mtolylphosphonium)-o-xylene Silylene
  • Preparation of a,a´-bis(tri-m-tolylphosphonium)-o-xylenedibromide
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of dibromosilane
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of silylene
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Application
  • References
  • 6.4.2 Iminosilylene: LSiCp* {L = bis(2,6-diisopropylphenyl)-imidazolin-2-iminato, Cp* = Me5C5}
  • Method 1: Synthesis of iminosilylene LSiCp*
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Method 2: Synthesis of iminosilylene LSiCp*
  • Synthesis of imidazolin-2-iminato dibromosilane (LSiBr2)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Synthesis of iminosilylene LSiCp*
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • Waste disposal
  • References
  • 6.4.3 Bis(trimethylsilyl)phosphinosilylene: [LSi-P(SiMe3)2] {L = PhC(NtBu)2}
  • Preparation of phosphinosilylene [LSi-P(SiMe3)2](L = PhC(NtBu)2)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Application
  • References
  • 6.4.4 N-Heterocyclic Carbene-Stabilized Silylene Monohydride: RSi:(Me4NHC)H
  • (R = tBu3Si, Me4NHC = 1,3,4,5-tetramethylimidazol-2- ...
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Attention!
  • Application
  • References
  • 7 - MULTIPLE BONDING IN SILICON COMPOUNDS
  • 7.1 A HIGHLY TWISTED DISILENE:(tBu2MeSi)2Si]Si(SiMetBu2)2
  • Preparation of tetrakis(di-tbutylmethylsilyl)disilene (Method A)
  • Apparatus
  • Chemicals
  • Experimental procedure (Method A)
  • Preparation of tetrakis(di-tbutylmethylsilyl)disilene (Method B)
  • Apparatus
  • Chemicals
  • Experimental procedure (Method B)
  • Waste disposal
  • Application
  • References
  • 7.2 SILYL ANIONeSUBSTITUTED SILENE:{(tBu2MeSi)2(THF2Li)}SieSi]Ad(OSiMetBu2)
  • (AD [ADAMANTYL)
  • Synthesis of silyl anion-substituted silene
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • 7.3 ARSASILENE: LSi(H)AsH, {L]CH(MeC]NAr)2, Ar[ 2,6-iPr2C6H3}
  • Preparation of arsasilene LSi(H)AsH, {LCH(MeCNAr)2, Ar=2,6-iPr2C6H3}
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Attention!
  • Application
  • References
  • 7.4 TWO ZWITTERIONICPHOSPHASILENES: PHOSPHASILENE 1
  • [LSi(SiMe3)]P(SiMe3)] {L]PhC(NtBu)2}AND A HALF-PARENT PHOSPHASILENE2
  • LSi]PH [L]CH{(C]CH2)CMe(NAr)2}
  • Ar [2,6-iPr2C6H3]
  • Phosphasilene 2: LSiPH [LCH{(CCH2)CMe(NAr)2}
  • Ar=2,6-iPr2C6H3]
  • Preparation of bis(phosphido)silane LSi(PH2)2
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of phosphidosilane chloride LSi(PH2)Cl
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of phosphasilene 2 (LSiPH)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Attention!
  • Application
  • Preparation of phosphasilene 1 [LSi(SiMe3)P(SiMe3)] (LPhC(NtBu)2)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Phosphasilene 1: [LSi(SiMe3)P(SiMe3)] {LPhC(NtBu)2}
  • References
  • 7.5 TETRASILYL-SUBSTITUTEDTRISILAALLENE: 1,1,3,3-TETRAKIS(DItBUTYLMETHYLSILYL)TRISILAALLENE
  • Preparation of 1,1,3,3-tetrakis(di-tbutylmethylsilyl)trisilaallene
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Application
  • References
  • 8 - SILICON-BASED LIGANDS FOR TRANSITION METAL COORDINATION
  • 8.1 SILICON(II)-BASED SiCSi PINCER ARENE: [(LSi)2-1,3-O2-4,6-tBu2-C6H2]
  • L [PhC(NtBu)2
  • Synthesis of SiCSi bis(silylene)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Application
  • References
  • Preparation of bis(silylene) nickel complex [{(LSi)2P(TMS)}Ni(COD)] {L = PhC(NtBu)2}
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Application
  • References
  • Preparation of disiloxane [LSiH(Cl)OSiH(Cl)L] precursor {L = PhC(NtBu)2}
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of disilylenoxane (LSi)2O {L = PhC(NtBu)2}
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of bis(silylene) oxide nickel complex [(LSiOSIL)Ni(COD)]
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Application
  • References
  • Preparation of pincer-type ligand SiNSi
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of [SiNSi]FeCl2 complex
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Application
  • References
  • Preparation of ferrocenyl bis(silylene) (LSi-Fc-SiL) (Fc = ferrocenediyl, L = PhC(NtBu)2
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of ferrocene-based CoI complex: {LSi-Fc-SiL (Fc = ferrocenediyl, L = PhC(NtBu)2)}
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Attention!
  • Application
  • References
  • Preparation of bis(silylene) titanium(II) complex [(?5-C5H5)2Ti (PMe3)2]
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of [(?5-C5H5)2Ti(LSiCl)2] {L = PhC(NtBu)2}
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Application
  • References
  • Preparation of [L1Si(H)(CH2)NHC] {L1 = CH(CCH2)(CMe)(NAr)2, Ar = 2,6-iPr2C6H3}
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of [L2Si(CH2)NHC]NiBr2
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Application
  • References
  • 9 - SILYLENES, SILYLAMINOSILYLENE, DISILANE, SILANIMINE, SILACYCLOHEXADIENONES, BIS(SILYL)-ALKENES, AND HYDROSILANIMINE
  • 9.1 SYNTHESIS OF AN N-HETEROCYCLIC SILYLENE BY DEHYDROHALOGENATION OF HYDROCHLOROSILANE
  • Outline placeholder
  • Preparation of (CH)2(tBuN)2SiHCl
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of N-heterocyclic silylene
  • Chemicals
  • Attention!
  • Experimental procedure
  • Application
  • References
  • Preparation of the NHC-stabilized silole silylene
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Application
  • References
  • Preparation of NHC-stabilized silylaminosilylene
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Application
  • References
  • Preparation of aminodisilane Ar(SiMe3)NSiHClSiCl2N(SiMe3)Ar
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Application
  • References
  • Preparation of the donor-free silanimine
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Application
  • References
  • Preparation of the base-stabilized silacyclohexadienones
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Application
  • References
  • Preparation of aminochlorosilane Ar(SiMe3)NSiHCl2
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Preparation of the NHC-stabilized silylene Ar(SiMe3)N(Cl)Si(IiPr)
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Preparation of 1,2-bis(silyl)-alkenes
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of trimethoxylsilyl-substituted alkenes
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • Preparation of base-stabilized 1-hydrosilanimine
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Application
  • References
  • Preparation of (IMes)Yb[N(SiMe3)2]2
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Preparation of silylamine
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • 10 - SYNTHESIS OF FUNCTIONALIZED SILSESQUIOXANES AS MOLECULAR TEMPLATES FOR HYBRID MATERIALS
  • Synthesis of octakis{3-[(2-hydroxyethyl)dimethylammonio]propyl}octasilsesquioxane chloride via nucleophilic substitution
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Characterization
  • Synthesis of heptaisobutyl[2-{4-(1-naphthyl)phenyl}ethenyl]octasilsesquioxane via silylative coupling of monovinylheptaisob ...
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Characterization
  • Attention!
  • Synthesis of octakisl[2-{4-(9-anthracenyl)phenyl}ethenyl]octasilsesquioxane via cross-metathesis of octavinylsilsesquioxane ...
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Characterization
  • Attention!
  • Synthesis of heptaisobutyl[11-hydroxyundecenyl]octasilsesquioxane via hydrosilylation of monohydridoheptaisobutylsilsesquio ...
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Characterization
  • Attention!
  • Synthesis of (tetrakis({1,1,2,2,3,3,4,4-octafluoropentyloxypropyl}dimethylsiloxy))tetrakis{3-glycidoxypropyl}dimethylsiloxy ...
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Characterization
  • Attention!
  • Synthesis of di[9,19-(E)-4-bromostyrylmethyl]-1,3,5,7,11,13,15,17-octaphenylpentacyclo-[11.7.1.13,11.15,17.17,15]decasiloxa ...
  • Apparatus
  • Chemicals
  • Experimental procedure
  • 3A-b: cis and trans mixture of di[9,19-(E)-4-bromostyrylmethyl]-1,3,5,7,11,13,15,17-octaphenylpentacyclo[11.7.1.13,11.15,17 ...
  • Characterization
  • Attention!
  • Synthesis of di[9,19-(E)-4-(trifluoromethyl)styrylphenyl]-1,3,5,7,11,13,15,17 octaphenylpentacyclo-[11.7.1.13,11.15,17.17,1 ...
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Characterization
  • Attention!
  • References
  • 11 - LITHIUM TRIS(2,4,6-TRIISOPROPYLPHENYL)DISILENIDE: A VERSATILE REAGENT FOR THE TRANSFER OF THE DISILENYL GROUP
  • Preparation of Tip2SiSiTipLi·dme2
  • Apparatus
  • Chemicals
  • General
  • Experimental procedure
  • 1H NMR
  • Waste disposal
  • Application
  • References
  • 12 - NEW PHOSPHINE-STABILIZED SI(II)-COMPLEXES: SILICON(II)-HYDRIDE AND SILACYCLOPROPYLIDENE
  • General procedures
  • Improved synthesis of dimethyl-N,N´-bis(tert-butyl)silazane (2)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Selected NMR data
  • Improved synthesis of cyclic diaminochlorophosphine 1 (3)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Selected NMR data
  • Synthesis of imino-phosphine 3 (4)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Selected NMR data
  • Application
  • Synthesis of phosphine-aminodichlorosilane complex 4 (6)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Selected NMR data
  • Application
  • Alternative procedure
  • Synthesis of phosphine-stabilized silicon(II)-hydride 5 (6)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Selected spectroscopic data
  • Synthesis of phosphine-stabilized silacyclopropene 6 (7)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Selected spectroscopic data
  • Synthesis of phosphine-stabilized silacyclopropylidene 7 (7)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Selected spectroscopic data
  • Alternative procedure
  • References
  • 13 - (MONOSODIUMOXY)ORGANOALKOXYSILANES (REBROV SALTS)-POLYFUNCTIONAL MONOMERS FOR SILICONE SYNTHESES
  • Preparation of (monosodiumoxy)organoalkoxysilanes
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Attention!
  • Application
  • References
  • 14 - SILICON(II) AS A SYNTHON FOR THE ACCESS OF DIFFERENT SILICON(IV) AND SILICON(II) COMPOUNDS
  • Preparation of [PhC(NtBu)2]Si(H)(Cl)NHNCPh2 (3)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of [CH{(CCH2)(CMe)(2,6-iPr2C6H3N)2}]Si(H)NH2 (4)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Attention!
  • Preparation of [CH{(CCH2)(CMe)(2,6-iPr2C6H3N)2}]Si(H)NHNH2 (5)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of [CH{(CCH2)(CMe)(2,6-iPr2C6H3N)2}]Si(H)NHNHMe (6)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • Preparation of [CH{(CCH2)(CMe)(2,6-iPr2C6H3N)2}]SiF(C6F5) (3)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of [PhC(NtBu)2]SiFCl(C6F5) (4)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of [CH{(CCH2)(CMe)(2,6-iPr2C6H3N)2}]SiF(4-C6F4CF3) (5)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of [CH{(CCH2)(CMe)(2,6-iPr2C6H3N)2}]SiF(4-C5F4N) (6)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of [PhC(NtBu)2]SiFCl(4-C6F4CF3) (7)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of [PhC(NtBu)2]SiFCl(4-C5F4N) (8)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of [CH{(CCH2)(CMe)(2,6-iPr2C6H3N)2}]SiH(C6F5) (9)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of [PhC(NtBu)2]SiFCl(4-C6F4H) (10)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of [CH{(CCH2)(CMe)(2,6-iPr2C6H3N)2}]SiH(1,3,5-C6F3H2) (11)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • References
  • Preparation of [PhC(NtBu)2]Si(OtBu)Fe(CO)4 (3)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of [PhC(NtBu)2]Si(Cl)B(C6F5)3 (4)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of [PhC(NtBu)2]Si(Cl)(9-BBN) (5)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • Preparation of [PhC(NtBu)2]Si(H)BH3 (3)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Synthesis of LSiCl(BH3) (2):
  • Synthesis of LSiH(BH3) (3):
  • Application
  • References
  • 15 - SILENE, SILAIMINE, AND SILETANE DERIVATIVES
  • Outline placeholder
  • Outline placeholder
  • Preparation of E-[N(SiMe3)2](?1-Me5C5)SiSi(?1-Me5C5)[N(SiMe3)2] (4)
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Characterization
  • Application
  • References
  • Preparation of PhC(NtBu)2Si(Cl)N(2,6-iPr2C6H3)
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Characterization
  • Application
  • Waste disposal
  • References
  • Preparation of E-[N(SiMe3)2](?1-Me5C5)SiSi(?1-Me5C5)[N(SiMe3)2]
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure (2, 3)
  • Characterization
  • Experimental procedure (4)
  • Characterization
  • Application
  • References
  • 16 - SYNTHESIS OF A ZWITTERIONIC 2,4-DISILA-1,3-DIPHOSPHACYCLOBUTADIENE COMPOUND
  • Preparation of 2,4-disila-1,3-diphosphacyclobutadiene {(PhC(NtBu)2)2Si2P2} (2)
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Characterization
  • Application
  • Apparatus
  • Chemicals
  • Preparation of 3
  • Characterization
  • Chemicals
  • Characterization
  • Waste disposal
  • References
  • 17 - SILANETRIOLS AND ALUMINOSILICATES
  • Structures of silanetriols
  • Application
  • References
  • Preparation
  • Apparatus
  • Attention!
  • Experimental procedure
  • Characterization data for 5-7
  • Synthesis and characterization data of 8
  • Synthesis and characterization data of 9 and 10
  • Synthesis and characterization data of 11 and 12
  • Application
  • References
  • 18 - SYNTHESIS OF SILICON(II) COMPOUNDS AND THEIR REACTIONS
  • Preparation of [PhC(NtBu)2]SiX (XCl and N(SiMe3)2)
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Characterization data
  • Application
  • Waste disposal
  • References
  • Preparation and disposal of KC8
  • Preparation of [PhC(NtBu)2]SiSi[PhC(NtBu)2]
  • Preparation of [PhC(NtBu)2]2{Si(CHPh2)}2O2
  • References
  • Preparation of 1,4-disilabenzene
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Characterization data
  • Application
  • References
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Characterization data
  • Application
  • 19 - PREPARATION OF THE NHC (L1,2) AND ITS APPLICATION FOR SYNTHESIZING LEWIS BASE-STABILIZED DICHLOROSILYLENE L1,2SICL2
  • Applications
  • Apparatus
  • Attention!
  • Caution!
  • Waste disposal
  • Synthesis of bis(2,6-diisopropylphenyl)imidazol-2-ylidene L1
  • Method 1
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Characterization
  • Attention!
  • Method 2
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Characterization
  • Attention!
  • Synthesis of bis(2,4,6-trimethylphenyl)imidazol-2-ylidene L2
  • Synthesis of L1SiCl2
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Characterization
  • Attention!
  • Alternative synthesis of L1SiCl2
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Characterization
  • Attention!
  • Synthesis of L2SiCl2
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Attention!
  • Characterization
  • References
  • 20 - OCTAAMMONIUM POSS AS A BUILDING BLOCK FOR CONSTRUCTING NANOHYBRID MATERIALS
  • Preparation of octaammonium POSS
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of octavinyl POSS
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • 21 - TUNGSTEN- AND RUTHENIUM-SILYLENE COMPLEXES
  • Preparation of Cp*(OC)2(H)WSi(H)[C(SiMe3)3] (Cp*=?5-C5Me5)
  • Apparatus
  • Chemicals
  • Experimental procedure (Method A) (1)
  • Method B (2)
  • Attention!
  • Application
  • References
  • Preparation of Cp*(OC)(H)RuSi(H)[C(SiMe3)3] (Cp*=?5-C5Me5)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Attention!
  • Application
  • References
  • 22 - 1,1-DI-TERT-BUTYLSILACYCLOPROPANES
  • Preparation of hexa-tert-butyl-cyclotrisilane (t-Bu2Si)3
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of 1,1-di-tert-butyl-siliranes
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • Preparation of 1,1-di-tert-butyl-iminosiletans
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste treatment
  • References
  • 23 - POLYSILANES, POLYCARBOSILANES, DIOXADISILACYCLOHEXANE, AND POLYSILOXANES
  • Preparation of branched polysilanes
  • References
  • Preparation of bis(4-(but-3-enyl)phenyl)methylsilane
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of 4-(but-3-enyl)phenyldimethylsilane
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of hyperbranched polymers
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Apparatus
  • Chemicals
  • Caution!
  • Experimental procedure
  • References
  • Preparation of (acetoxymethyl)methoxydimethylsilane
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of 2,2,5,5-tetramethyl-1,4-dioxa-2,5-disilacyclohexane (1)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of a,?-bis(hydroxymethyl)polydimethylsiloxanes
  • Apparatus
  • Chemicals
  • Experimental procedure
  • References
  • Preparation of bis((2-methylpent-4-en-2-yl)oxy)silane
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of 2,2,8,8-tetramethyl-1,7-dioxa-6-silaspiro[5.5]undecane
  • Apparatus
  • Chemicals
  • Experimental procedure
  • References
  • 24 - SYNTHESIS OF N-(SILYLMETHYL)AMIDES OF CARBOXYLIC ACIDS AND RELATED COMPOUNDS
  • 24.1 Introduction
  • 24.2 N-Alkylation of Amides by Halomethylsilanes
  • 24.3 Acylation of N-(silylmethyl)amines
  • 24.3.1 Acylation of N-(silylmethyl)amines by Acyl Halides
  • 24.3.2 Acylation of N-(silylmethyl)amines by an Acid
  • 24.3.3 Acylation of N-(silylmethyl)amines by Anhydride
  • 24.3.4 Acylation of N-(silylmethyl)amines by Esters
  • 24.3.5 Acylation of N-(silylmethyl)sulfinamides
  • 24.4 Interaction of a-Nitrogen Carbanion With a Chlorosilane
  • 24.5 Miscellaneous Preparations
  • 24.6 Conclusions
  • References
  • 25 - CARBENE ADDUCTS OF SILICON(IV) CHLORIDES: VERSATILE REAGENTS FOR CARBENE TRANSFER AND SOURCES FOR CATIONIC SILICON(IV) ...
  • Preparation of (C5H10N2)SiCl4. Route 1: starting from trichloromethane
  • Apparatus
  • Chemicals
  • Attention!
  • Caution!
  • Experimental procedure
  • Preparation of (C5H10N2)SiCl4. Route 2: starting from hexachlorodisilane
  • Apparatus
  • Chemicals
  • Attention!
  • Caution!
  • Experimental procedure
  • Characterization data
  • Application
  • Preparation of (C5H12N2)SiCl4
  • Apparatus
  • Chemicals
  • Attention!
  • Caution!
  • Experimental procedure
  • Characterization data
  • Application
  • Preparation of (C5H10N2)SiCl3H
  • Apparatus
  • Chemicals
  • Attention!
  • Caution!
  • Experimental procedure
  • Characterization data
  • Application
  • Preparation of (C5H10N2)SiCl2H2
  • Apparatus
  • Chemicals
  • Attention!
  • Caution!
  • Experimental procedure
  • Characterization data
  • Preparation of [(C5H10N2)SiCl3][BCl4]
  • Apparatus
  • Chemicals
  • Attention!
  • Caution!
  • Experimental procedure
  • Characterization data
  • Preparation of [(C5H10N2)2SiCl3][BCl4]
  • Apparatus
  • Chemicals
  • Attention!
  • Caution!
  • Experimental procedure
  • Characterization data
  • Preparation of (C5H10N2)Si(C2F5)2Cl2
  • Apparatus
  • Chemicals
  • Attention!
  • Caution!
  • Experimental procedure
  • Characterization data
  • Preparation of [(C5H10N2)2SiCl2H][(C2F5)2SiCl3]
  • Apparatus
  • Chemicals
  • Attention!
  • Caution!
  • Experimental procedure
  • Characterization data
  • References
  • 26 - CONTROLLING N-OLIGOSILANE CONFORMATION BY STRETCHING ON A STAFFANE RACK
  • 26.1 The Overall Plan
  • 26.1.1 The Utility of Conformationally Controlled n-Oligosilanes
  • 26.1.2 Conformation Control by Racking
  • 26.1.3 General Synthetic Procedures
  • 26.2 The Victims: Terminally Doubly Functionalized n-Oligosilanes
  • 26.2.1 Dodecamethylcyclohexasilane (3)
  • 26.2.2 Permethylated a,?-Dichlorooligosilanes, Cl(SiMe2)nCl (n=2-7)
  • 26.2.3 Hexadecamethyl-1,8-diphenyloctasilane (43)
  • 26.3 The Shackles
  • 26.3.1 1,8-Diallylhexadecamethyloctasilane
  • 26.3.2 Hexadecamethyl-1,8-bis(3-hydroxy-n-propyl)octasilane
  • 26.3.3 Hexadecamethyl-1,8-di-(3-tosyloxy-n-propyl)octasilane
  • 26.4 The Racks: [n]Staffane-3,3(n-1)dithiols
  • 26.4.1 [n]Staffane-3,3(n-1)-dithiolacetates (5[n])
  • 26.4.2 Conversion of Diacetylated to Free [n]Staffane-3,3(n-1)-dithiols, 5[n] to 4[n]
  • 26.5 Mounting the Victims
  • 26.5.1 [2]Staffane-1,8-bis(1-thiopropyl)hexadecamethyloctasilane (1[2,8])
  • 26.5.2 [2]Staffane-1,6-bis(1-thiopropyl)dodecamethylhexasilane (1[2,6]) (25)
  • 26.6 Stretching the Victim
  • 26.6.1 Photochemical Chain Abridgment
  • [2]Staffane-1,4-bis(1-thiopropyl)octamethyltetrasilane (1[2,4])
  • [2]Staffane-1,5-bis(1-thiopropyl)decamethylpentasilane (1[2,5]) (25)
  • [2]Staffane-1,7-bis(1-thiopropyl)tetradecamethylheptasilane (1[2,7])
  • 26.6.2 Attachment to the Rack Through Sulfones
  • [2]Staffane-1,6-bis(1-sulfonylpropyl)dodecamethylhexasilane (2[2,6])
  • [2]Staffane-1,4-bis(1-sulfonylpropyl)octamethyltetrasilane (2[2,4])
  • 26.7 Summary
  • Acknowledgment
  • References
  • 27 - BIS-SILYL CHELATE LIGAND PRECURSOR XANTSILH2 AND SOME RUTHENIUM XANTSIL COMPLEXES
  • Preparation of xantsilH2 [4,5-bis(dimethylsilyl)-9,9-dimethylxanthene]
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of cis-Ru(xantsil)(CO)4
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of Ru(xantsil)(CO)(?6C6H5Me)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of Ru(xantsil)(CO)(PCy3)(A)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Catalytic Reaction: preparation of (E)-2-(Ethyldimethylsilyl)stilbene
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Attention!
  • Application
  • References
  • 28 - SILYL(SILYLENE) COMPLEXES OF IRON AND RUTHENIUM
  • Preparation of Cp*Fe(CO)(SiMes2)SiMe3
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of Cp*Ru(CO)(SiMes2)SiMe3
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Attention!
  • Application
  • References
  • 29 - COBALT-METHYLIDYNE-SILANETRIOL AS PRECURSOR FOR CATALYTIC HYDROFORMYLATION IN A TWO-PHASE SYSTEM
  • Preparation of Co3CO9CSi(OR)3, R = CH2CH2(CH2CH2)9OH
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Application
  • References
  • 30 - PREPARATION OF THE SICS THREE- AND THE SIO2C2 FIVE-MEMBERED RING SYSTEM
  • Preparation of silacyclopropane from LSitBu (L=PhC(NtBu)2) and 4,4´-bis(dimethylamino)thiobenzophenone (6c)
  • Attention!
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Characterization
  • Preparation of the SiO2C2 five-membered ring system from LSiC(SiMe3)3 and 3,5-di-tert-butyl-o-benzoquinone (6c)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Characterization
  • Waste disposal
  • References
  • 31 - PREPARATION OF SIF4(NH3)2 AND ITS HIGHER AMMONIATE SIF4(NH3)2·2NH3
  • Preparation of SiF4(NH3)22NH3 and SiF4(NH3)2
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • 32 - SILANOLS AND SILSESQUIOXANES
  • Preparation of 1,1,2-trimethylpropylsilanetriol
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • Preparation of 2,4,6-triisopropylphenylsilanetriol
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • Preparation of phenylsilanetriol
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • Preparation of 1,3-bis(2,4,6-triisopropylphenyl)disiloxanetetraol
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • Preparation of 1,3-diphenyldisiloxanetetraol
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • Preparation of [i-PrSi(OH)O]4
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • Preparation of [i-BuSi(OH)O]4
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • Preparation of cis,trans-[i-PrSi(OH)O]3
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • Preparation of 1,1-dihydroxy-1-silacyclopentane
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of 1,1,3,3-bis(1,4-butanediyl)disiloxane
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of 1,1,3,3-bis(1,4-butanediyl)disiloxane-1,3-diol
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of 2,2,4,4-bis(1,4-butanediyl)-6,6-dimethylcyclotrisiloxane
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of 2,2,4,4-bis(1,4-butanediyl)-6,6,8,8-tetramethylcyclotetrasiloxane
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of 2,2,6,6-bis(1,4-butanediyl)-4,4,8,8-tetramethylcyclotetrasiloxane
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • Preparation of 1,1,3,3,5,5-hexamethyltrisiloxane-1,5-diol
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of 1,1,3,3,5,5,7,7,9,9-decamethylpentasiloxane
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of 2,2-diphenyl-4,4,6,6,8,8-hexamethylcyclotetrasiloxane
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Preparation of 2,2,4,4,6,6,10,10,12,12,14,14-dodecamethylspiro[7.7]heptasiloxane
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • Preparation of hexa(tert-butylsilsesquioxane)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • Preparation of hexa(isopropylsilsesquioxane)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • Reference
  • Preparation of octa(isopropylsilsesquioxane)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • Preparation of 6-8-6-tricyclic laddersiloxane
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • Preparation of syn-8-8-8-tricyclic laddersiloxane
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • References
  • 33 - HYDRIDO-SILYL COMPLEXES OF CHROMIUM WITH METAL-HYDROGEN-SILICON THREE-CENTER BONDS
  • Preparation of (?6C6Me6)(CO)2Cr(H)SiHPh2
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Attention!
  • References
  • 34 - SOL-GEL PROCESSING OF ALKOXYSILYL-SUBSTITUTED METAL COMPLEXES
  • Preparation of {Cu[H2NCH2CH2NH(CH2)3Si(OMe)3]}(OAc)2
  • Apparatus
  • Chemicals
  • Attention!
  • Procedure
  • References
  • 35 - TERTIARY ALKYL SUBSTITUTED OCTASILSESQUIOXANES
  • Preparation of tertiary alkyl-substituted octasilsesquioxanes
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Application
  • Waste disposal
  • References
  • 36 - O-(DIMESITYLBORYL)(DIMETHYLSILYL)BENZENE: A SYSTEM OF INTRAMOLECULAR SI&z.sbnd
  • H BOND ACTIVATION BY O-BORYL GROUP
  • Preparation of o-(C6H4)(BMes2)(SiMe2H)
  • Apparatus
  • Chemicals
  • Attention!
  • Experimental procedure
  • Application
  • References
  • 37 - ORGANOSILICON SYNTHESIS FOR CONSTRUCTION OF ORGANOSILICON CLUSTERS
  • 37.1 Introduction
  • 37.2 General Procedures for the Synthesis of Organosilicon Compounds
  • 37.2.1 Chlorosilanes
  • 37.2.2 Solvents
  • 37.3 SiliconCarbon Bond Formation
  • 37.3.1 Nucleophilic Substitution of Halosilanes with Grignard and Organolithium Reagents
  • Alkylation of chlorosilane with a Grignard reagent (6)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Partial alkylation of chlorosilane with a Grignard reagent (7)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Alkylation of chlorosilane with a Grignard reagent in the presence of a copper(I) cyanide catalyst (3)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Alkylation of chlorosilane with an organolithium reagent (8)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • 37.3.2 Hydrosilylation of Alkenes with Hydrosilanes
  • Hydrosilylation with a hexachloroplatinic(IV) acid catalyst (9,10)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Hydrosilylation with a transition metal catalyst (11-13)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Hydrosilylation with a base catalyst (14)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • 37.4 SiliconSilicon Bond Formation
  • 37.4.1 Wurtz-Type Coupling of Chlorosilanes with Alkali Metals
  • Wurtz-type coupling of monochlorosilane with lithium (18)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Wurtz-type coupling of dichlorosilane with lithium (19)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Wurtz-type coupling of two kinds of chlorosilanes with lithium (20,21)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • 37.4.2 Coupling of Halosilanes with Silyl Anions
  • Coupling of chlorosilane with silyllithium (24)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Coupling of chlorosilane with silylpotassium (25)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Coupling of chlorosilane with a silylmagnesium reagent (26)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • 37.5 Functional Group Transformation of Chlorosilanes
  • Outline placeholder
  • Transformation of chlorosilane to hydrosilane (27)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Selective transformation of dichlorosilane to monohydrosilane (28)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Transformation of chlorosilane to alkoxysilane (28)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Transformation of chlorosilane to aminosilane (29)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • 37.6 Functional Group Transformation of Hydrosilanes
  • Outline placeholder
  • Transformation of hydrosilane to chlorosilane with carbon tetrachloride and benzoyl peroxide (24)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Transformation of hydrosilane to chlorosilane with carbon tetrachloride in the presence of a palladium(II) chloride catalys ...
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Transformation of hydrosilane to chlorosilane with hydrochloric acid in the presence of a palladium(II) chloride catalyst (30)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Selective transformation of dihydrosilane to monochlorosilane with copper(II) chloride in the presence of a copper(I) iodid ...
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Transformation of hydrosilane to bromosilane with bromine (34)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Transformation of hydrosilane to bromosilane with N-bromosuccinimide (NBS) (35)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Transformation of hydrosilane to alkoxysilane with alcohol in the presence of a palladium(II) chloride catalyst (36)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • 37.7 Functional Group Transformation of Aminosilanes
  • Outline placeholder
  • Transformation of aminosilane to chlorosilane with hydrogen chloride (24)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • 37.8 Replacement of an Organic Group on a Silicon Atom by a Functional Group
  • Outline placeholder
  • Dephenylchlorination of phenylsilane (24)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Dephenylfunctionalization of phenylsilane (44)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Partial dephenylfunctionalization of polyphenylsilane (45)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Demethylchlorination of hexamethyldisilane (43)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Demethylchlorination of octamethyltrisilane (43)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • 37.9 Synthesis of Organosilicon Clusters
  • 37.9.1 Synthesis of Cyclotetrasilane-Fused Octasilacuneane (24)
  • Wurtz-type coupling of 1,1-di-tert-butyl-1,2-dichloro-2,2-diphenyldisilane with lithium (24)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Tetramerization of 1,1,2,2-tetra-tert-butyl-3,3,4,4-tetraphenylcyclotetrasilane with sodium (24)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • 37.9.2 Synthesis of Cyclopentasilane-Fused Hexasilabenzvalene (34)
  • Wurtz-type coupling of 2,2-di-tert-butyl-1-chloro-1,1-diphenyldisilane with lithium (34)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Dilithiation of 1,4-dibromo-1,1,4,4-tetra-tert-butyl-2,2,3,3-tetraphenyltetrasilane and coupling of the resulting disilyl a ...
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Dephenylchlorination of 1,1,3,3-tetra-tert-butyl-2,2-dimethyl-4,4,5,5-tetraphenylcyclopentasilane with hydrogen chloride in ...
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Trimerization of 1,1,3,3-tetra-tert-butyl-4,4,5,5-tetrachloro-2,2-dimethylcyclopentasilane with sodium (34)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • 37.9.3 Synthesis of Tetrasilane-Bridged Bicyclo[4.1.0]heptasil-1(6)-ene (54)
  • Dilithiation of 1,4-dibromo-1,1,4,4-tetra-tert-butyl-2,2,3,3-tetraphenyltetrasilane and coupling of the resulting disilyl a ...
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Dephenylchlorination of 1,1,4,4-tetra-tert-butyl-2,2,3,3-tetramethyl-5,-5,6,6-tetraphenylcyclohexasilane with hydrogen chlo ...
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • Dimerization of 1,1,4,4-tetra-tert-butyl-2,2,3,3-tetrachloro-5,5,6,6-tetramethylcyclohexasilane with sodium (54)
  • Apparatus
  • Chemicals
  • Experimental procedure
  • Waste disposal
  • References
  • INDEX
  • Back Cover

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